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PhD in Physics and Astronomy: Quantum Optics of Giant Rydberg Excitons in Cuprous Oxide

This funding opportunity has expired.

Key facts

Application deadline 15 September 2019
Start date October 2019
Duration 3.5 years
Level of study Postgraduate research
Award type PhD studentship
Number of studentships 1

There has been renewed recent interest in cuprous oxide as a technological material because of potential applications in photocatalysis and solar energy harvesting.

Cuprous oxide (Cu2O) is one the oldest, and yet least well-known, semiconductor material. It has a slightly larger band gap than silicon, which means that the single crystal form of the material is slightly transparent in the visible part of the spectrum. Cuprous oxide exists in nature and beautiful deep-red gemstones have been cut and polished from natural single crystal material.

Cuprous oxide has an additional extraordinary optoelectronic property. In most semiconductors, photons with energy just larger than the band gap can produce bound electron-hole states known has excitons. These excitons are not unlike hydrogen atoms trapped in the solid-state: they consist of an electron orbiting a positive core (hole). Like hydrogen, the excitons also have excited states, which typically take the form of Rydberg series, and at cryogenic temperatures it is usually possible to observe a small number (3 or 4) excited states.

Due to the unusual nature of the Fermi surface in cuprous oxide however, very high principal quantum number excitons states can exist. A recent Nature paper reported Rydberg series extending up to n = 25.This means that the exciton in cuprous oxide is an extraordinarily stable quantum object, and one that can be readily manipulated with light.

The aim of this PhD project is to investigate the quantum optical properties of this unique material and explore its potential to be exploited for quantum technologies. You will join a well-funded medium-sized research group including two postdoctoral researchers and five PhD students.

You will be trained in the use of a range of advanced spectroscopic characterisation tools, including ultrafast lasers and time-resolved transient FT-IR. You will also be trained in the latest cryogenic techniques, and additional materials characterisation tools including scanning-electron microscopy (SEM), confocal microscopy, and Raman spectroscopy. It is likely that you will be required to spend some time abroad working with our international collaborators.

Supervisors

Contact

Jessica Phillips

Jessica Phillips

Education Support Officer

Email:
phillipsj21@cardiff.ac.uk
Telephone:
+44 (0)29 2068 7114

Funding details

Tuition fee support Full UK/EU tuition fees
Maintenance stipend Doctoral stipend matching UK Research Council National Minimum

Eligibility criteria

Residency Open to all UK/EU students without further restrictions
Academic criteria

Applicants must have obtained, or be about to obtain, a First Class or Upper Second Class degree or Master’s degree in a relevant discipline.

Applicants whose first language is not English are normally expected to meet the minimum University requirements (e.g. 6.5 IELTS).

The funding for this project is open to UK/EU residents only.

Contact

Jessica Phillips

Jessica Phillips

Education Support Officer

Email:
phillipsj21@cardiff.ac.uk
Telephone:
+44 (0)29 2068 7114

Consideration is automatic upon application for admission to the Doctor of Philosophy in Physics and Astronomy with a start date of October 2019.

Please select “No, I am not self-funding my research” when asked whether you are self-funding your research.

We reserve the right to close applications early should sufficient applications be received.

Additionally, please submit a personal statement and CV with your application. In the research proposal section of your application, please specify that the Research Project Title is “Quantum Optics of Giant Rydberg Excitons in Cuprous Oxide” and the supervisor is Dr Stephen Lynch.

We reserve the right to close applications early should sufficient applications be received.

Contact

Jessica Phillips

Jessica Phillips

Education Support Officer

Email:
phillipsj21@cardiff.ac.uk
Telephone:
+44 (0)29 2068 7114

Eligible research programmes