EPSRC iCase PhD in Chemistry: Synthesis of boron-nitride-carbon molecular hybrids for sensing and thermal management applications
|Application deadline||6 May 2019|
|Start date||1 October 2019|
|Level of study||Postgraduate research|
|Award type||PhD studentship|
|Number of studentships||1|
This project is to tackle the challenge of gaining controlled functions of organic semiconductors using extended polycyclic aromatic hydrocarbons (PAHs), encoding the functionalization that defines the properties and the self-assembly properties via a site-specific doping of the aromatic framework.
The aim of this project can be achieved through the substitution of the C=C bonds with isostructural and isoelectronic boron-nitrogen couples (BN) and exploiting the polarity of their bonds to program the functional properties. By changing the dopant/carbon ratio and the doping pattern, one can tailor the desired chemical, optical, heat dissipation and molecular recognition properties of the organic semiconductor.
The idea is to prepare materials for two main applications:small molecule gas sensing and thermal management.
Project aims and methods
Scientific Objectives (SOs1-4). You will prepare molecular graphenes starting from structurally programmed dendritic precursors (SOs1&2) in which aryl units are substituted in given positions with borazine rings (B3N3). It is envisaged that the planarization (SO3) will yield the formation of molecular graphenes featuring doping units arranged in a predetermined pattern (SOs4). This will lead to isoelectronic fully planar p-conjugated modules each encoded with a specific BN-doping pattern and concentration, the latter dictating both the energy bandgap, thermal dissipation and chemical recognition properties.
The first part of the project will be centered on the development of synthetic methodologies allowing the controlled insertion of B3N3-rings into nanographene structures.
The expected academic returns are:
- control on the concentration and arrangement of the doping units
- establishment of a doping/property relation.
Technologic Objectives (TOs1-2).By engineering top-gate bottom-contact (TGBC) and bottom-gate bottom-contact (BGBC) devices, we will measure the charge-carrier mobilities of the materials as thin films and nanostructure morphologies.
The devices will then be exposed to gases (CO2, CO). A specific binding of the compounds is expected to occur selectively at the polar doping sites, ultimately affecting the source-drain current of the transistors(TO1). Given the close proximity between the analytes and the semiconducting materials, the best sensing system prototype is expected to achieve detections limits down to the femto molar range, with a low-cost, reliable sensing technology.
A pronounced variation in the selectivity is expected when operating with materials doped with different doping concentrations. In a second avenue, we will investigate the heat dissipation properties of the semiconductor (TO2).In general,all electronic devices and circuitry generate excess heat and thus require thermal management to improve reliability and prevent premature failure. In order to make efficient and cost-effective the removal of dissipated thermal energy from any devices, current technologies (e.g., heat sinks, thermoelectric coolers, forced air systems and fans, heat pipes to name a few) should be coupled with materials displaying high thermal conductivity.
Given the high thermal conductivity of boron nitride (BN), it is expected that the molecules developed in this project can replace current semiconductors and allow the development of even smaller devices and make our mobile phones and computers cooler and safer.
Professor of Organic Supramolecular Chemistry
|Tuition fee support||Full UK/EU tuition fees|
|Maintenance stipend||Doctoral stipend matching UK Research Council National Minimum|
|Residency||UK Research Council eligibility conditions apply|
You should hold or expect to gain a first class degree or a good 2.1 and/or an appropriate master’s level qualification (or their equivalent).
Applicants whose first language is not English will be required to demonstrate proficiency in the English language (IELTS 6.5 or equivalent).
The studentship is open to:
- UK students
- EU students who have been resident in the UK for three years at the course start date
- other candidates who can demonstrate a connection to the UK, usually through residency.
Consideration is automatic upon application for admission to the Doctor of Philosophy in Chemistry with an 1 October 2019 start date.
In the 'Research proposal and Funding' section of your application, please specify the project title and supervisors of this project and copy the project description in the text box provided.
Please select 'No, I am not self-funding my research' when asked whether you are self-funding your research.
Please add 'EPSRC Doctoral Training Partnership PhD in Chemistry' when asked 'Please provide the name of the funding you are applying for'.
We reserve the right to close applications early should sufficient applications be received.
Funding opportunity provided by: