Dr William Dlamini
Research Associate (with Prof Graham Hutchings)
Overview
Dr Dlamini's research interests focuses on the fundamental understanding of catalyzed reactions relevant to the production of clean transportation fuels, commodity chemicals and the solar-driven remediation of pollutants. This approach involves gaining insight on the metal-support interface, the active sites present in the functional material as well as the reaction mechanism. Typically, the study of conventional catalystic materials is done in parallel with tunable model systems such as carbons etc. See our recent publications for more details.
Publication
2023
- Delarmelina, M., Dlamini, M., Pattisson, S., Davies, P. R., Hutchings, G. and Catlow, C. 2023. The effect of dissolved chlorides on the photocatalytic degradation properties of titania in wastewater treatment. Physical Chemistry Chemical Physics 25, pp. 4161-4176. (10.1039/D2CP03140J)
- Ou, X., Dlamini, M. W., Tomatis, M., Davies, P. R., Hutchings, G. J. and Hardacre, C. 2023. Catalytic treatment of high ionic strength wastewater from shale gas production. In: Modern Developments in Catalysis., Vol. 2. World Scientific Publishing Europe Ltd., (10.1142/9781800612013_0001)
2022
- Hutchings, G. J., Davies, P. R., Pattisson, S., Davies, T. E., Morgan, D. J. and Dlamini, M. W. 2022. Facile synthesis of a porous 3D g-C3N4 photocatalyst for the degradation of organics in shale gas brines. Catalysis Communications 169, article number: 106480. (10.1016/j.catcom.2022.106480)
2020
- Phaahlamohlaka, T. N., Dlamini, M. W., Kumi, D. O., Forbes, R., Jewell, L. L. and Coville, N. J. 2020. Co inside hollow carbon spheres as a Fischer-Tropsch catalyst: spillover effects from Ru placed inside and outside the HCS. Applied Catalysis A: General 599, article number: 117617. (10.1016/j.apcata.2020.117617)
- Caswell, T., Dlamini, M. W., Miedziak, P. J., Pattisson, S., Davies, P. R., Taylor, S. H. and Hutchings, G. J. 2020. Enhancement in the rate of nitrate degradation on Au- and Ag-decorated TiO2 photocatalysts. Catalysis Science and Technology 10(7), pp. 2083-2091. (10.1039/C9CY02473E)
- Dlamini, M. W., Phaahlamohlaka, T. N., Kumi, D. O., Forbes, R., Jewell, L. L. and Coville, N. J. 2020. Post doped nitrogen-decorated hollow carbon spheres as a support for Co Fischer-Tropsch catalysts. Catalysis Today 342, pp. 99-110. (10.1016/j.cattod.2019.01.070)
2018
- Kumi, D. O., Dlamini, M. W., Phaahlamohlaka, T. N., Mhlanga, S. D., Coville, N. J. and Scurrell, M. S. 2018. Selective CO methanation over Ru supported on carbon spheres: the effect of carbon functionalization on the reverse water gas shift reaction. Catalysis Letters 148(11), article number: 3502. (10.1007/s10562-018-2546-6)
- Kumi, D. O., Phaahlamohlaka, T. N., Dlamini, M. W., Mangezvo, I. T., Mhlanga, S. D., Scurrell, M. S. and Coville, N. J. 2018. Effect of a titania covering on CNTS as support for the Ru catalysed selective CO methanation. Applied Catalysis B: Environmental 232, pp. 492-500. (10.1016/j.apcatb.2018.02.016)
- Phaahlamohlaka, T. N., Dlamini, M. W., Mogodi, M. W., Kumi, D. O., Jewell, L. L., Billing, D. G. and Coville, N. J. 2018. A sinter resistant Co Fischer-Tropsch catalyst promoted with Ru and supported on titania encapsulated by mesoporous silica. Applied Catalysis A: General 552, pp. 129-137. (10.1016/j.apcata.2017.12.015)
2017
- Phaahlamohlaka, T. N., Kumi, D. O., Dlamini, M. W., Forbes, R., Jewell, L. L., Billing, D. G. and Coville, N. J. 2017. Effects of Co and Ru Intimacy in Fischer-Tropsch catalysts using hollow carbon sphere supports: assessment of the hydrogen spillover processes. ACS Catalysis 7(3), pp. 1568-1578. (10.1021/acscatal.6b03102)
2016
- Phaahlamohlaka, T. N., Kumi, D. O., Dlamini, M. W., Jewell, L. L. and Coville, N. J. 2016. Ruthenium nanoparticles encapsulated inside porous hollow carbon spheres: A novel catalyst for Fischer-Tropsch synthesis. Catalysis Today 275, pp. 76-83. (10.1016/j.cattod.2015.11.034)
- Dlamini, M. W., Coville, N. J. and Scurrell, M. S. 2016. Microwave treatment: a facile method for the solid state modification of potassium-promoted iron on silica Fischer-Tropsch catalysts. RSC Advances 6(27), pp. 22222-22231. (10.1039/C5RA26628A)
2015
- Dlamini, W., Coville, N. and Scurrell, M. 2015. Microwave radiation in the modification of iron Fischer-Tropsch catalysts. Journal of Molecular Catalysis A: Chemical 409, pp. 19-25. (10.1016/j.molcata.2015.06.014)
- Dlamini, M. W., Kumi, D. O., Phaahlamohlaka, T. N., Lyadov, A. S., Billing, D. G., Jewell, L. L. and Coville, N. J. 2015. Carbon spheres prepared by hydrothermal synthesis-A support for bimetallic iron cobalt Fischer-Tropsch catalysts. ChemCatChem 7(18), pp. 3000-3011. (10.1002/cctc.201500334)
Articles
- Delarmelina, M., Dlamini, M., Pattisson, S., Davies, P. R., Hutchings, G. and Catlow, C. 2023. The effect of dissolved chlorides on the photocatalytic degradation properties of titania in wastewater treatment. Physical Chemistry Chemical Physics 25, pp. 4161-4176. (10.1039/D2CP03140J)
- Hutchings, G. J., Davies, P. R., Pattisson, S., Davies, T. E., Morgan, D. J. and Dlamini, M. W. 2022. Facile synthesis of a porous 3D g-C3N4 photocatalyst for the degradation of organics in shale gas brines. Catalysis Communications 169, article number: 106480. (10.1016/j.catcom.2022.106480)
- Phaahlamohlaka, T. N., Dlamini, M. W., Kumi, D. O., Forbes, R., Jewell, L. L. and Coville, N. J. 2020. Co inside hollow carbon spheres as a Fischer-Tropsch catalyst: spillover effects from Ru placed inside and outside the HCS. Applied Catalysis A: General 599, article number: 117617. (10.1016/j.apcata.2020.117617)
- Caswell, T., Dlamini, M. W., Miedziak, P. J., Pattisson, S., Davies, P. R., Taylor, S. H. and Hutchings, G. J. 2020. Enhancement in the rate of nitrate degradation on Au- and Ag-decorated TiO2 photocatalysts. Catalysis Science and Technology 10(7), pp. 2083-2091. (10.1039/C9CY02473E)
- Dlamini, M. W., Phaahlamohlaka, T. N., Kumi, D. O., Forbes, R., Jewell, L. L. and Coville, N. J. 2020. Post doped nitrogen-decorated hollow carbon spheres as a support for Co Fischer-Tropsch catalysts. Catalysis Today 342, pp. 99-110. (10.1016/j.cattod.2019.01.070)
- Kumi, D. O., Dlamini, M. W., Phaahlamohlaka, T. N., Mhlanga, S. D., Coville, N. J. and Scurrell, M. S. 2018. Selective CO methanation over Ru supported on carbon spheres: the effect of carbon functionalization on the reverse water gas shift reaction. Catalysis Letters 148(11), article number: 3502. (10.1007/s10562-018-2546-6)
- Kumi, D. O., Phaahlamohlaka, T. N., Dlamini, M. W., Mangezvo, I. T., Mhlanga, S. D., Scurrell, M. S. and Coville, N. J. 2018. Effect of a titania covering on CNTS as support for the Ru catalysed selective CO methanation. Applied Catalysis B: Environmental 232, pp. 492-500. (10.1016/j.apcatb.2018.02.016)
- Phaahlamohlaka, T. N., Dlamini, M. W., Mogodi, M. W., Kumi, D. O., Jewell, L. L., Billing, D. G. and Coville, N. J. 2018. A sinter resistant Co Fischer-Tropsch catalyst promoted with Ru and supported on titania encapsulated by mesoporous silica. Applied Catalysis A: General 552, pp. 129-137. (10.1016/j.apcata.2017.12.015)
- Phaahlamohlaka, T. N., Kumi, D. O., Dlamini, M. W., Forbes, R., Jewell, L. L., Billing, D. G. and Coville, N. J. 2017. Effects of Co and Ru Intimacy in Fischer-Tropsch catalysts using hollow carbon sphere supports: assessment of the hydrogen spillover processes. ACS Catalysis 7(3), pp. 1568-1578. (10.1021/acscatal.6b03102)
- Phaahlamohlaka, T. N., Kumi, D. O., Dlamini, M. W., Jewell, L. L. and Coville, N. J. 2016. Ruthenium nanoparticles encapsulated inside porous hollow carbon spheres: A novel catalyst for Fischer-Tropsch synthesis. Catalysis Today 275, pp. 76-83. (10.1016/j.cattod.2015.11.034)
- Dlamini, M. W., Coville, N. J. and Scurrell, M. S. 2016. Microwave treatment: a facile method for the solid state modification of potassium-promoted iron on silica Fischer-Tropsch catalysts. RSC Advances 6(27), pp. 22222-22231. (10.1039/C5RA26628A)
- Dlamini, W., Coville, N. and Scurrell, M. 2015. Microwave radiation in the modification of iron Fischer-Tropsch catalysts. Journal of Molecular Catalysis A: Chemical 409, pp. 19-25. (10.1016/j.molcata.2015.06.014)
- Dlamini, M. W., Kumi, D. O., Phaahlamohlaka, T. N., Lyadov, A. S., Billing, D. G., Jewell, L. L. and Coville, N. J. 2015. Carbon spheres prepared by hydrothermal synthesis-A support for bimetallic iron cobalt Fischer-Tropsch catalysts. ChemCatChem 7(18), pp. 3000-3011. (10.1002/cctc.201500334)
Book sections
- Ou, X., Dlamini, M. W., Tomatis, M., Davies, P. R., Hutchings, G. J. and Hardacre, C. 2023. Catalytic treatment of high ionic strength wastewater from shale gas production. In: Modern Developments in Catalysis., Vol. 2. World Scientific Publishing Europe Ltd., (10.1142/9781800612013_0001)