Yr Athro Damien Murphy

2022

• Magri, G., Folli, A. and Murphy, D. M. 2022. Monitoring the substrate-induced spin-state distribution in a Cobalt(II)-Salen complex by EPR and DFT. European Journal of Inorganic Chemistry 2022(9), article number: e202101071. (10.1002/ejic.202101071)
• Barter, M. et al. 2022. Design considerations of a dual mode X-band EPR resonator for rapid in-situ microwave heating. Applied Magnetic Resonance (10.1007/s00723-022-01463-1)
• Blackaby, W. J. M. et al. 2022. Extreme g-Tensor anisotropy and its insensitivity to structural distortions in a family of linear two-coordinate Ni(I) Bis-N-heterocyclic carbene complexes. Inorganic Chemistry 61(3), pp. 1308-1315. (10.1021/acs.inorgchem.1c02413)

2021

• Pezzetta, C., Folli, A., Matuszewska, O., Murphy, D., Davidson, R. W. M. and Bonifazi, D. 2021. peri‐xanthenoxanthene (PXX): a versatile organic photocatalyst in organic synthesis. Advanced Synthesis and Catalysis 363(20), pp. 4740-4753. (10.1002/adsc.202100030)
• Spencer, J. N., Folli, A., Ren, H. and Murphy, D. M. 2021. An EPR Investigation of defect structure and electron transfer mechanism in mixed-conductive LiBO2-V2O5 glasses. Journal of Materials Chemistry A: materials for energy and sustainability 9(31), pp. 16917-16927. (10.1039/D1TA02352G)
• Richards, T. et al. 2021. A new clean approach to water disinfection using catalytic in situ generation of reactive oxygen species. Nature Catalysis 4, pp. 575-585. (10.1038/s41929-021-00642-w)
• Crombie, C. M. et al. 2021. Enhanced selective oxidation of benzyl alcohol via in situ H2O2 production over supported Pd-based catalysts. ACS Catalysis 11, pp. 2701–2714. (10.1021/acscatal.0c04586)
• Folli, A., Ritterskamp, N., Richards, E., Platts, J. A. and Murphy, D. M. 2021. Probing the structure of copper(II)-casiopeina type coordination complexes [Cu(O-O)(N-N)]+ by EPR and ENDOR spectroscopy. Journal of Catalysis 394, pp. 220-227. (10.1016/j.jcat.2020.07.016)
• Underhill, R. et al. 2021. Ambient base-free glycerol oxidation over bimetallic PdFe/SiO2 by in situ generated active oxygen species. Research on Chemical Intermediates 47, pp. 303-324. (10.1007/s11164-020-04333-2)

2020

• Bracci, M. et al. 2020. Paramagnetic species in catalysis research: a unified approach towards (the role of EPR in) heterogeneous, homogeneous and enzyme catalysis. In: Chechik, V., Murphy, D. M. and Bode, B. E. eds. Electron Paramagnetic Resonance., Vol. 27. Royal Society of Chemistry, pp. 1-46., (10.1039/9781839162534-00001)
• Spencer, J., Merrikin, D., Pope, S., Morgan, D., Carthey, N. and Murphy, D. 2020. CW EPR investigation of red-emitting CaS:Eu phosphors: rationalization of local electronic structure. Advanced Optical Materials 8(22), article number: 2001241. (10.1002/adom.202001241)
• Dordevic, L. et al. 2020. O-doped nanographenes: a pyrano/pyrylium route towards semiconducting cationic mixed-valence complexes. Angewandte Chemie International Edition 59(10), pp. 4106-4114. (10.1002/anie.201914025)
• Folli, A. et al. 2020. A novel dual mode X-band EPR resonator for rapid in situ microwave heating. Journal of Magnetic Resonance 310, article number: 106644. (10.1016/j.jmr.2019.106644)

2019

• Richards, E., Murphy, D. M. and Che, M. 2019. An EPR characterisation of stable and transient reactive oxygen species formed under radiative and non-radiative conditions. Research on Chemical Intermediates 45(12), pp. 5763-5779. (10.1007/s11164-019-04001-0)
• Luckham, S. L. J., Folli, A., Platts, J. A., Richards, E. and Murphy, D. M. 2019. Unravelling the photochemical transformations of chromium(I) 1,3 Bis(diphenylphosphino), [Cr(CO)4(dppp)]+, by EPR spectroscopy. Organometallics 38(12), pp. -. (10.1021/acs.organomet.9b00226)
• Sampford, K. R. et al. 2019. Twisting the arm: structural constraints in bicyclic expanded-ring N-heterocyclic carbenes. Dalton Transactions, pp. -. (10.1039/C8DT04462G)

2018

• Spencer, J., Folli, A., Richards, E. and Murphy, D. M. 2018. Applications of electron paramagnetic resonance spectroscopy for interrogating catalytic systems. In: Chechik, V. and Murphy, D. M. eds. Electron Paramagnetic Resonance., Vol. 26. Royal Society of Chemistry, pp. 130-170., (10.1039/9781788013888-00130)
• Liu, Z., Mariani, A., Wu, L., Ritson, D., Folli, A., Murphy, D. and Sutherland, J. 2018. Tuning the reactivity of nitriles using Cu(ii) catalysis - potentially prebiotic activation of nucleotides. Chemical Science 9(35), pp. 7053-7057. (10.1039/C8SC02513D)
• Spencer, J., Stevens, J., Perry, C. and Murphy, D. M. 2018. An EPR investigation of binding environments by N-donor chelating exchange resins for Cu extraction from aqueous media. Inorganic Chemistry 57(17), pp. 10857-10866. (10.1021/acs.inorgchem.8b01519)
• Buckingham, M. A., Cunningham, W., Bull, S. D., Buchard, A., Folli, A., Murphy, D. M. and Marken, F. 2018. Electrochemically driven C-H hydrogen abstraction processes with the tetrachloro-phthalimido-N-oxyl (Cl4PINO) catalyst. Electroanalysis 30(8), pp. 1698-1705. (10.1002/elan.201800147)
• Sciutto, A., Fermi, A., Folli, A., Battisti, T., Beames, J., Murphy, D. and Bonifazi, D. 2018. Customizing photoredox properties of PXX-based dyes through energy level rigid shifts of frontier molecular orbitals. Chemistry - a European Journal 24(17), pp. 4382-4389. (10.1002/chem.201705620)
• Folli, A. et al. 2018. Improving the selectivity of photocatalytic NOx abatement through improved O2 reduction pathways using Ti0.909W0.091O2Nx semiconductor nanoparticles: from characterisation to photocatalytic performance. ACS Catalysis 8(8), pp. 6927-6938. (10.1021/acscatal.8b00521)

2017

• Blackaby, W. J. M. et al. 2017. Mono- and dinuclear Ni(i) products formed upon bromide abstraction from the Ni(i) ring-expanded NHC complex [Ni(6-Mes)(PPh3)Br]. Dalton Transactions 47(3), pp. 769-782. (10.1039/C7DT04187J)
• Vallotto, C., Williams, H. E., Murphy, D. M., Ayres, Z., Edge, R., Newton, M. and Wedge, C. 2017. An Electron Paramagnetic Resonance (EPR) spectroscopy study on the γ-irradiation sterilization of the pharmaceutical excipient l-histidine: Regeneration of the radicals in solution. International Journal of Pharmaceutics 533(1), pp. 315-319. (10.1016/j.ijpharm.2017.09.068)
• Ritterskamp, N., Sharples, K., Richards, E., Folli, A., Chiesa, M., Platts, J. A. and Murphy, D. M. 2017. Understanding the coordination modes of [Cu(acac)2(imidazole)n=1,2] adducts by EPR, ENDOR, HYSCORE, and DFT analysis. Inorganic Chemistry 56(19), pp. 11862-11875. (10.1021/acs.inorgchem.7b01874)
• Liu, X. et al. 2017. Catalytic partial oxidation of cyclohexane by bimetallic Ag/Pd nanoparticles on magnesium oxide. Chemistry - A European Journal 23(49) (10.1002/chem.201605941)
• Constantinides, C. P., Carter, E., Eisler, D., Beldjoudi, Y., Murphy, D. M. and Rawson, J. M. 2017. Effects of Halo-substitution on 2'-Chloro-5'-halo-phenyl-1,2,3,5-dithiadiazolyl Radicals: A Crystallographic, Magnetic and EPR Case Study. Crystal Growth and Design 17(6), pp. 3017-3029. (10.1021/acs.cgd.6b01700)

2016

• Pelties, S., Carter, E., Folli, A., Mahon, M. F., Murphy, D. M., Whittlesey, M. K. and Wolf, R. 2016. Influence of ring-expanded N-heterocyclic carbenes on the structures of half-sandwich Ni(I) complexes: an x-ray, electron paramagnetic resonance (EPR), and electron nuclear double resonance (ENDOR) study. Inorganic Chemistry 55(21), pp. 11006-11017. (10.1021/acs.inorgchem.6b01540)
• Et-Tarhouni, Z., Carter, E., Murphy, D. M., Griffiths, P. C., Mansour, O. T., King, S. M. and Paul, A. 2016. Quantifying the micellar structure formed from hydrocarbon-fluorocarbon surfactants. Colloids and Surfaces A: Physiochemical and Engineering Aspects 492, pp. 255-262. (10.1016/j.colsurfa.2015.12.015)
• Hallett, A. J., O'Brien, T., Carter, E., Kariuki, B., Murphy, D. M. and Ward, B. D. 2016. Copper(II) complexes of pyridine-oxazoline (Pyox) ligands: coordination chemistry, ligand stability, and catalysis. Inorganica Chimica Acta 441, pp. 86-94. (10.1016/j.ica.2015.10.032)
• Conte, M., Liu, X., Murphy, D. M., Taylor, S. H., Whiston, K. and Hutchings, G. J. 2016. Insights into the reaction mechanism of cyclohexane oxidation catalysed by molybdenum blue nanorings. Catalysis Letters 146(1), pp. 126-135. (10.1007/s10562-015-1660-y)
• Chechik, V., Carter, E. and Murphy, D. 2016. Electron paramagnetic resonance. Oxford Chemistry Primers. Oxford: Oxford University Press.

2015

• Healy, M. R. et al. 2015. EPR/ENDOR and computational study of outer sphere interactions in copper complexes of phenolic oximes. Inorganic Chemistry 54(17), pp. 8465-8473. (10.1021/acs.inorgchem.5b01180)
• Liu, X. et al. 2015. Liquid phase oxidation of cyclohexane using bimetallic Au–Pd/MgO catalysts. Applied Catalysis A: General 504, pp. 373-380. (10.1016/j.apcata.2015.02.034)
• Carter, E. and Murphy, D. M. 2015. The role of low valent transition metal complexes in homogeneous catalysis: an EPR investigation. Topics in Catalysis 58(12-13), pp. 759-768. (10.1007/s11244-015-0417-6)
• Carter, E., Sharples, K. M., Platts, J. A. and Murphy, D. M. 2015. Structure determination of bound nitrogen-based adducts with copper(ii) acetylacetonato; an EPR, ENDOR and DFT study. Physical Chemistry Chemical Physics 17(17), pp. 11445-11454. (10.1039/C5CP00559K)
• Carter, E. and Murphy, D. 2015. Homogeneous catalytic transformations investigated by EPR spectroscopy. In: Gilbert, B. C., Chechik, V. and Murphy, D. eds. Electron Paramagnetic Resonance., Vol. 24. Royal Society of Chemistry, pp. 148-193., (10.1039/9781782620280-00148)

2014

• Bedford, R. B., Brenner, P. B., Carter, E., Gallagher, T., Murphy, D. M. and Pye, D. R. 2014. Iron-catalyzed borylation of alkyl, allyl, and aryl halides: isolation of an iron(I) boryl complex. Organometallics 33(21), pp. 5940-5943. (10.1021/om500847j)
• Liu, X. et al. 2014. Molybdenum blue nano-rings: an effective catalyst for the partial oxidation of cyclohexane. Catalysis Science & Technology 5, pp. 217-227. (10.1039/C4CY01213E)
• Bedford, R. B. et al. 2014. Iron phosphine catalyzed cross-coupling of tetraorganoborates and related group 13 nucleophiles with alkyl halides. Organometallics 33(20), pp. 5767-5780. (10.1021/om500518r)
• Bedford, R. B. et al. 2014. Expedient iron-catalyzed coupling of alkyl, benzyl and allyl halides with aylboronic esters. Chemistry - A European Journal 20(26), pp. 7935-7938. (10.1002/chem.201402174)
• Constantinides, C. P., Eisler, D. J., Alberola, A., Carter, E., Murphy, D. M. and Rawson, J. M. 2014. Weakening of the pi*-pi* dimerisation in 1,2,3,5-dithiadiazolyl radicals: structural, EPR, magnetic and computational studies of dichlorophenyl dithiadiazolyls, Cl2C6H3CNSSN. Crystengcomm 16(31), pp. 7298-7312. (10.1039/C4CE00308J)
• Hicks, J. et al. 2014. A two-coordinate manganese(0) complex with an unsupported Mn-Mg bond: allowing access to low coordinate homo- and heterobimetallic compounds. Journal of the American Chemical Society 136(14), pp. 5283-5286. (10.1021/ja5021348)
• Meenakshisundaram, S., Nowicka, E., Carter, E., Murphy, D. M., Knight, D. W., Bethell, D. and Hutchings, G. J. 2014. The benzaldehyde oxidation paradox explained by the interception of peroxy radical by benzyl alcohol. Nature Communications 5, pp. ., article number: 3332. (10.1038/ncomms4332)
• Bedford, R. B. et al. 2014. TMEDA in iron-catalyzed Kumada coupling: amine adduct versus homoleptic "ate" complex formation. Angewandte Chemie International Edition 53(7), pp. 1804-1808. (10.1002/anie.201308395)

2013

• Poulten, R. C. et al. 2013. Synthesis, electronic structure, and magnetism of [Ni(6-Mes)2]+: a two-coordinate nickel(I) complex stabilized by bulky N-heterocyclic carbenes. Journal of the American Chemical Society 135(37), pp. 13640-13643. (10.1021/ja407004y)
• Sharples, K. M., Carter, E., Hughes, C. E., Harris, K. D. M., Platts, J. A. and Murphy, D. M. 2013. An ENDOR and DFT analysis of hindered methyl group rotations in frozen solutions of bis(acetylacetonato)-copper(ii). Physical Chemistry Chemical Physics 15(36), pp. 15214-15222. (10.1039/c3cp52464g)
• Griffiths, P. C., Mauro, N., Murphy, D. M., Carter, E., Richardson, S. C. W., Dyer, P. and Ferruti, P. 2013. Self-assembled PAA-based nanoparticles as potential gene and protein delivery systems. Macromolecular Bioscience 13(5), pp. 641-649. (10.1002/mabi.201200462)
• Page, M. J. et al. 2013. Three-coordinate nickel(I) complexes stabilised by six-, seven- and eight-membered ring N-heterocyclic carbenes: synthesis, EPR/DFT studies and catalytic activity. Chemistry - a European Journal 19(6), pp. 2158-2167. (10.1002/chem.201202950)
• Ab Rahim, M. H. et al. 2013. Oxidation of methane to methanol with hydrogen peroxide using supported gold-palladium alloy nanoparticles. Angewandte Chemie - International Edition 52(4), pp. 1280-1284. (10.1002/anie.201207717)
• Bedford, R. B. et al. 2013. Simplifying iron-phosphine catalysts for cross-coupling reactions. Angewandte Chemie - International Edition 52(4), pp. 1285-1288. (10.1002/anie.201207868)
• Morris, J. L., Reddington, S. C., Murphy, D. M., Jones, D. D., Platts, J. A. and Tippmann, E. M. 2013. Aryl azide photochemistry in defined protein environments. Organic Letters 15(4), pp. 728-731. (10.1021/ol3028779)
• Carter, E. et al. 2013. Formation of [Cr(CO)x(Ph2PN(iPr)PPh2)]+Structural Isomers by Reaction of Triethylaluminum with a ChromiumN,N-Bis(diarylphosphino)amine Complex [Cr(CO)4(Ph2PN(iPr)PPh2)]+: An EPR and DFT Investigation. Organometallics 32(6), pp. 1924-1931. (10.1021/om400029y)
• Constantinides, C. P. et al. 2013. Spin-triplet excitons in 1,3-diphenyl-7-(fur-2-yl)-1,4-dihydro-1,2,4-benzotriazin-4-yl. Chemical Communications 49(77), pp. 8662-8664. (10.1039/c3cc44899a)
• Carter, E., Hazeland, E. L., Murphy, D. M. and Ward, B. D. 2013. Structure, EPR/ENDOR and DFT characterisation of a [CuII(en)2](OTf)2 complex. Dalton Transactions 42(42), pp. 15088-15096. (10.1039/c3dt51694f)

2012

• Hammond, C. et al. 2012. Catalytic and mechanistic insights of the low-temperature selective oxidation of methane over Cu-promoted Fe-ZSM-5. Chemistry - a European Journal 18(49), pp. 15735-15745. (10.1002/chem.201202802)
• Owen, M. E., Carter, E., Hutchings, G. J., Ward, B. D. and Murphy, D. M. 2012. Influence of counterions on the structure of bis(oxazoline) copper(II) complexes; an EPR and ENDOR investigation. Dalton Transactions 41(36), pp. 11085-11092. (10.1039/C2DT31273E)
• Hammond, C. et al. 2012. Direct catalytic conversion of methane to methanol in an aqueous medium by using copper-promoted Fe-ZSM-5. Angewandte Chemie - International Edition 51(21), pp. 5129-5133. (10.1002/anie.201108706)
• Zamani, S., Carter, E., Murphy, D. M. and Van Doorslaer, S. 2012. Probing differences in binding of methylbenzylamine enantiomers to chiral cobalt(II) salen complexes. Dalton Transactions 41(22), pp. 6861-6870. (10.1039/C2DT30207A)
• Saiman, M. I. et al. 2012. Involvement of surface-bound radicals in the oxidation of toluene using supported Au-Pd nanoparticles. Angewandte Chemie. International Edition 51(24), pp. 5981-5985. (10.1002/anie.201201059)
• Stephen, E. et al. 2012. Redox non-innocence of thioether crowns: elucidation of the electronic structure of the mononuclear Pd(III) complexes [Pd([9]aneS3)2]3+and [Pd([18]aneS6)]3+. Inorganic Chemistry 51(3), pp. 1450-1461. (10.1021/ic2017006)
• Van Doorslaer, S. and Murphy, D. M. 2012. EPR spectroscopy in catalysis. In: Drescher, M., Jeschke, G. and Bordignon, E. eds. EPR Spectroscopy: Applications in Chemistry and Biology. Topics in Current Chemistry Vol. 321. Berlin: Springer, pp. 1-39., (10.1007/978-3-642-28347-5)
• Adams, C. J. et al. 2012. Iron(I) in Negishi cross-coupling reactions. Journal of the American Chemical Society 134(25), pp. 10333-10336. (10.1021/ja303250t)
• Vinck, E., Carter, E., Murphy, D. M. and Doorslaer, S. V. 2012. Observation of an organic acid mediated spin state transition in a Co(II)-Schiff base complex: an EPR, HYSCORE, and DFT study. Inorganic Chemistry 51(15), pp. 8014-8024. (10.1021/ic300058p)
• Conte, M., Liu, X., Murphy, D. M., Whiston, K. and Hutchings, G. J. 2012. Cyclohexane oxidation using Au/MgO: an investigation of the reaction mechanism. Physical Chemistry Chemical Physics 14(47), pp. 16279-16285. (10.1039/c2cp43363j)
• Hammond, C. et al. 2012. Cover Picture: Catalytic and mechanistic insights of the low-temperature selective oxidation of methane over Cu-promoted Fe-ZSM-5 (Chem. Eur. J. 49/2012). Chemistry - A European Journal 18(49), pp. 15557. (10.1002/chem.201290208)

2011

• Murphy, D. M. et al. 2011. Visualizing diastereomeric interactions of chiral amine-chiral copper salen adducts by EPR spectroscopy and DFT. Inorganic Chemistry 50(15), pp. 6944-6955. (10.1021/ic200113u)
• Carter, E. et al. 2011. Structure and pulsed EPR characterization of N,N′-bis(5-tert-butylsalicylidene)-1,2-cyclohexanediamino-vanadium(IV) oxide and its adducts with propylene oxide. Dalton Transactions 40(28), pp. 7454-7462. (10.1039/c1dt10378d)
• Woodul, W. D. et al. 2011. A neutral, monomeric germanium(I) radical. Journal of the American Chemical Society 133(26), pp. 10074-10077. (10.1021/ja204344e)
• Murphy, D. M., McDyre, L., Carter, E., Stasch, A. and Jones, C. 2011. A CW-EPR, ENDOR and special TRIPLE resonance study of a novel magnesium ketyl radical. Magnetic Resonance in Chemistry 49(4), pp. 159-163. (10.1002/mrc.2721)
• Alberola, A., Carter, E., Constantinides, C. P., Eisler, D. J., Murphy, D. M. and Rawson, J. M. 2011. Crystal structures, EPR and magnetic properties of 2-ClC6H4CNSSN˙ and 2,5-Cl2C6H3CNSSN˙. Chemical Communications 47(9), pp. 2532-2534. (10.1039/c0cc04296j)
• McDyre, L. et al. 2011. Intramolecular formation of a CrI(bis-arene) species via TEA activation of [Cr(CO)4(Ph2P(C3H6)PPh2)]+: sn EPR and DFT investigation. Organometallics 30(17), pp. 4505-4508. (10.1021/om2006062)
• Caretti, I., Carter, E., Fallis, I. A., Murphy, D. M. and Van Doorslaer, S. 2011. Interactions of an asymmetric amine with a non-C2 symmetric Cu-salen complex: An EPR/ENDOR and HYSCORE investigation. Physical Chemistry Chemical Physics 13(45), pp. 20427-20434. (10.1039/c1cp22522g)
• Rickard, D. T., Hatton, B., Murphy, D. M., Butler, I., Oldroyd, A. and Hann, A. 2011. FeS-induced radical formation and its effect on plasmid DNA. Aquatic Geochemistry 17(4-5), pp. 545-566. (10.1007/s10498-010-9116-x)
• Murphy, D. M., McNamara, K., Richardson, P., Sanchez-Romaguera, V., Winpenny, R. E. and Yellowlees, L. J. 2011. Electrochemical and spectroelectrochemical studies of complexes of 1,10-phenanthroline-5,6-dione. Inorganica Chimica Acta 374(1), pp. 435-441. (10.1016/j.ica.2011.02.050)

2010

• Griffiths, P. C. et al. 2010. Interaction of an endosomolytic polyamidoamine ISA23 with vesicles mimicking intracellular membranes: A SANS/EPR study. Macromolecular Bioscience 10(8), pp. 963-973. (10.1002/mabi.201000040)
• Luzon, J. et al. 2010. Spin density studies on p-O2NC6F4CNSSN: A heavy p-block organic ferromagnet. Physical Review B: Condensed Matter and Materials Physics 81(14), article number: 144429. (10.1103/PhysRevB.81.144429)
• Carter, E., Fallis, I. A., Murphy, D. M., Willock, D. J., Van Doorslaer, S. and Vinck, E. 2010. Probing the role of weak outer sphere interactions (H-bonds) in VO(3,5-tBu2-salophen) – Epoxide adducts by EPR, ENDOR and HYSCORE. Chemical Physics Letters 486(1-3), pp. 74-79. (10.1016/j.cplett.2009.12.066)
• Carter, E. et al. 2010. Experimental observation of spin delocalisation onto the aryl-alkynyl ligand in the complexes [Mo(C=CAr)(Ph2PCH2CH2PPh2)(η-C7H7)]+ (Ar = C6H5, C6H4-4-F; C7H7 = cycloheptatrienyl): an EPR and ENDOR investigation. Dalton Transactions 39(47), pp. 11424-11431. (10.1039/c0dt00642d)
• McDyre, L., Hamilton, T., Murphy, D. M., Cavell, K. J., Gabrielli, W. F., Hanton, M. J. and Smith, D. M. 2010. A cw EPR and ENDOR investigation on a series of Cr(I) carbonyl complexes with relevance to alkene oligomerization catalysis: [Cr(CO)(4)L](+) (L = Ph2PN(R)PPh2, Ph2P(R)PPh2). Dalton Transactions 39(33), pp. 7792-7799. (10.1039/C0DT00127A)
• Vinck, E., Murphy, D. M., Fallis, I. A., Strevens, R. R. and Van Doorslaer, S. 2010. Formation of a Cobalt(III)-Phenoxyl Radical Complex by Acetic Acid Promoted Aerobic Oxidation of a Co(II)salen Complex. Inorganic Chemistry 49(5), pp. 2083-2092. (10.1021/ic901849e)
• Jones, C., McDyre, L., Murphy, D. M. and Stasch, A. 2010. Magnesium(i) reduction of benzophenone and anthracene: first structural characterisation of a magnesium ketyl. Chemical Communications 46(9), pp. 1511-1513. (10.1039/b922002j)

2009

• Green, J., Carter, E. and Murphy, D. M. 2009. Interaction of molecular oxygen with oxygen vacancies on reduced TiO2: Site specific blocking by probe molecules. Chemical Physics Letters 477(4-6), pp. 340-344. (10.1016/j.cplett.2009.07.002)
• Green, J., Carter, E. and Murphy, D. M. 2009. An EPR investigation of acetonitrile reactivity with superoxide radicals on polycrystalline TiO2. Research on Chemical Intermediates 35(2), pp. 145-154. (10.1007/s11164-008-0022-4)
• Murphy, D. M., Fallis, I. A., Carter, E., Willock, D. J., Landon, J., Van Doorslaer, S. and Vinck, E. 2009. Enantioselective binding of structural epoxide isomers by a chiral vanadyl salen complex: a pulsed EPR, cw-ENDOR and DFT investigation. Physical Chemistry Chemical Physics 11(31), pp. 6757-6769. (10.1039/b907807j)
• Van Doorslaer, S., Caretti, I., Fallis, I. A. and Murphy, D. M. 2009. The power of electron paramagnetic resonance to study asymmetric homogeneous catalysts based on transition-metal complexes. Coordination Chemistry Reviews 253(15-16), pp. 2116-2130. (10.1016/j.ccr.2008.12.010)
• Vinck, E., Murphy, D. M., Fallis, I. A. and Doorslaer, S. 2009. A Pulsed EPR and DFT Investigation of the Stabilization of Coordinated Phenoxyl Radicals in a Series of Cobalt Schiff-Base Complexes. Applied Magnetic Resonance 37(1-4), pp. 289-303. (10.1007/s00723-009-0059-6)
• Bennati, M. and Murphy, D. M. 2009. Electron paramagnetic resonance spectra in the solid state. In: Brustolon, M. and Giamello, E. eds. Electron paramagnetic resonance: a practitioner's toolkit. Hoboken, N.J.: Wiley, pp. 195-249., (10.1002/9780470432235.ch6)
• Murphy, D. M. 2009. EPR (Electron paramagnetic resonance) spectroscopy of polycrystalline oxide systems. In: Jackson, S. D. and Hargreaves, J. S. J. eds. Metal Oxide Catalysis. Weinheim: Wiley-VCH, pp. 1-50., (10.1002/9783527626113.ch1)
• Carter, E. and Murphy, D. 2009. Structure-function relationships and mechanistic pathways in homogeneous catalysis as probed by ENDOR spectroscopy. In: Yarwood, J., Douthwaite, R. and Duckett, S. eds. Spectroscopic properties of inorganic and organometallic chemistry., Vol. 40. Specialist periodical report Cambridge: Royal Society of Chemistry, pp. 355-384., (10.1039/b715580h)

2008

• Vinck, E., Van Doorslaer, S., Murphy, D. M. and Fallis, I. A. 2008. The electronic structure of N,N′-bis(3,5-di-tert-butylsalicylidene)-1,2-cyclohexane-diamino cobalt(II). Chemical Physics Letters 464(1-3), pp. 31-37. (10.1016/j.cplett.2008.08.103)
• Amoroso, A. J. et al. 2008. The synthesis and structure of terpyridine-N-oxide complexes of copper(II) perchlorate. Dalton Transactions(4), pp. 506-513. (10.1039/b713444d)
• Laidlaw, W. M., Denning, R. G., Murphy, D. M. and Green, J. C. 2008. Solvent dependence of the g-anisotropy in the ESR of cyanide-bridged mixed-valence complexes. Dalton Transactions(44), pp. 6257-6264. (10.1039/b810224d)
• Murphy, D. M., Fallis, I. A., Willock, D. J., Landon, J. H., Carter, E. and Vinck, E. 2008. Discrimination of geometrical epoxide isomers by ENDOR spectroscopy and DFT calculations: the role of hydrogen bonds. Angewandte Chemie. International Edition 47(8), pp. 1414-1416. (10.1002/anie.200703537)
• Murphy, D. M. and Chiesa, M. 2008. EPR of paramagnetic centres on solid surfaces. In: Gilbert, B. C. ed. Electron paramagnetic resonance., Vol. 21. Cambridge: Royal Society of Chemistry, pp. 105-130., (10.1039/b709153m)

2007

• Carter, E., Carley, A. F. and Murphy, D. M. 2007. Evidence for O2- Radical Stabilization at Surface Oxygen Vacancies on Polycrystalline TiO2. Journal of Physical Chemistry C 111(28), pp. 10630-10638. (10.1021/jp0729516)
• Griffiths, P. C. et al. 2007. Derivatizing weak polyelectrolytes-Solution properties, self-aggregation, and association with anionic surfaces of hydrophobically modified poly(ethylene imine). Journal of Colloid and Interface Science 314(2), pp. 460-469. (10.1016/j.jcis.2007.05.082)
• Carter, E., Carley, A. F. and Murphy, D. M. 2007. Free-Radical Pathways in the Decomposition of Ketones over Polycrystalline TiO2: The Role of Organoperoxy Radicals. ChemPhysChem 8(1), pp. 113-123. (10.1002/cphc.200600484)
• Morgan, A. J., Pleasance, B., Kinsey, H., Murphy, D. M. and Davies, M. S. 2007. The manganese relationships of ecophysiologically contrasting earthworm species (Lumbricus rubellus and Aporrectodea caliginosa) inhabiting manganese-mine soils. European Journal of Soil Biology 43(S1), pp. S297-S302. (10.1016/j.ejsobi.2007.08.030)
• Van Doorslaer, S., Murphy, D. M. and Fallis, I. A. 2007. Evaluating pi-pi stacking effects in macrocyclic transition metal complexes using EPR techniques. Research on Chemical Intermediates 33(8-9), pp. 807-823. (10.1163/156856707782169318)
• Chiesa, M., Giamello, E., Annino, G., Massa, C. A. and Murphy, D. M. 2007. Multi-frequency high-field EPR study of (H+)(e−) pairs localized at the surface of polycrystalline MgO. Chemical Physics Letters 438(4-6), pp. 285-289. (10.1016/j.cplett.2007.03.024)
• Ribeiro, M. F. et al. 2007. Improvement of toluene catalytic combustion by addition of cesium in copper exchanged zeolites. Applied Catalysis B - Environmental 70(1-4), pp. 384-392. (10.1016/j.apcatb.2006.01.027)
• van Doorslaer, S., Murphy, D. M. and Fallis, I. A. 2007. Evaluating π-π stacking effects in macrocyclic transition metal complexes using EPR techniques. Research on Chemical Intermediates 33(8-9), pp. 807-823. (10.1163/156856707782169318)

2006

• Conte, M. et al. 2006. Chemically Induced Fast Solid-State Transitions of ω-VOPO4 in Vanadium Phosphate Catalysts. Science 313(5791), pp. 1270-1273. (10.1126/science.1130493)
• Chiesa, M., Paganini, M. C., Giamello, E., Murphy, D. M., Di Valentin, C. and Pacchioni, G. 2006. Excess Electrons Stabilized on Ionic Oxide Surfaces. Accounts of Chemical Research 39(11), pp. 861-867. (10.1021/ar068144r)
• Bushell, J. A., Claybourn, M., Murphy, D. M. and Williams, H. E. 2006. An EPR, ENDOR and EIE study of γ-irradiated poly (lactide-co-glycolide) polymers. Magnetic Resonance in Chemistry 44(10), pp. 929-935. (10.1002/mrc.1880)
• Williams, H. E., Loades, V. C., Claybourn, M. and Murphy, D. M. 2006. Electron Paramagnetic Resonance Spectroscopy Studies of Oxidative Degradation of an Active Pharmaceutical Ingredient and Quantitative Analysis of the Organic Radical Intermediates Using Partial Least-Squares Regression. Analytical Chemistry 78(2), pp. 604-608. (10.1021/ac051697f)
• Murphy, D. M. and Farley, R. D. 2006. Principles and applications of ENDOR spectroscopy for structure determination in solution and disordered matrices. Chemical Society Reviews 35(3), pp. 249-268. (10.1039/b500509b)
• Baker, R. J., Jones, C., Mills, D. P., Murphy, D. M., Hey-Hawkins, E. and Wolf, R. 2006. The reactivity of gallium-(i), -(ii) and -(iii) heterocycles towards Group 15 substrates: attempts to prepare gallium-terminal pnictinidene complexes. Dalton Transactions(1), pp. 64-72. (10.1039/b511451a)

2005

• Baker, R. J., Farley, R. D., Jones, C., Mills, D. P., Kloth, M. and Murphy, D. M. 2005. An EPR and ENDOR Investigation of a Series of Diazabutadiene-Group 13 Complexes. Chemistry-a European Journal 11(10), pp. 2972-2982. (10.1002/chem.200401103)
• Alberola, A., Farley, R. D., Humphrey, S. M., McManus, G. D., Murphy, D. M. and Rawson, J. M. 2005. EPR studies on the thiophenodithiazolyl radical, C4H2S3N˙. Dalton Transactions(24), pp. 3838-3845. (10.1039/b508912c)
• Bushell, J. A., Claybourn, M., Williams, H. E. and Murphy, D. M. 2005. An EPR and ENDOR study of γ- and β-radiation sterilization in poly (lactide-co-glycolide) polymers and microspheres. Journal of Controlled Release 110(1), pp. 49-57. (10.1016/j.jconrel.2005.09.009)
• Antcliff, K. L., Baker, R. J., Jones, C., Murphy, D. M. and Rose, R. P. 2005. Reactions of a Gallium(II)-Diazabutadiene Dimer, [{{[(H)C(But)N]2}GaI}2], with [ME(SiMe3)2] (M = Li or Na; E = N, P, or As):  Structural, EPR, and ENDOR Characterization of Paramagnetic Gallium(III) Pnictide Complexes. Inorganic Chemistry 44(6), pp. 2098-2105. (10.1021/ic0486825)

2004

• Fallis, I. A., Murphy, D. M., Willock, D. J., Tucker, R. J., Farley, R. D., Jenkins, R. L. and Strevens, R. R. 2004. Direct Observation of Enantiomer Discrimination of Epoxides by Chiral Salen Complexes Using ENDOR. Journal of the American Chemical Society 126(48), pp. 15660-15661. (10.1021/ja045491s)
• Garcia, T., Solsona, B. E., Murphy, D. M., Antcliff, K. L. and Taylor, S. H. 2004. Deep oxidation of light alkanes over titania-supported palladium/vanadium catalysts. Journal of Catalysis 229(1), pp. 1-11. (10.1016/j.jcat.2004.09.018)

2003

• Tucker, R. J., Fallis, I. A., Farley, R. D., Murphy, D. M. and Willock, D. J. 2003. An ENDOR and DFT analysis of 'solvatochromic' effects in an oxovanadium (IV) complex. Chemical Physics Letters 380(5-6), pp. 758-766. (10.1016/j.cplett.2003.09.077)
• Baker, R. J., Edwards, P., Farley, R. D., Murphy, D. M., Platts, J. A. and Voss, K. E. 2003. Low valent carbonylvanadium complexes of the triphosphorus macrocycle 12[ane]P3Et3. Dalton Transactions(5), pp. 944-948. (10.1039/B211105P)

2002

• Farley, R. D. et al. 2002. An ENDOR study of oxomolybdenum(V) tris(pyrazolyl)borate complexes; identification of couplings to boron and other. Magnetic Resonance in Chemistry 40(11), pp. 683-686. (10.1002/mrc.1090)
• Purnell, I. J., Chiesa, M., Farley, R. D., Murphy, D. M., Rowlands, C. C., Paganini, M. C. and Giamello, E. 2002. Heterogeneity of surface colour centres on alkaline earth metal oxides as revealed through EPR/ENDOR spectroscopy. Magnetic Resonance in Chemistry 40(6), pp. 381-386. (10.1002/mrc.1028)
• Murphy, D. M., Fallis, I. A., Farley, R. D., Tucker, R. J., Avery, K. L. and Willock, D. J. 2002. Conformational changes of an oxovanadium complex probed by ENDOR spectroscopy and DFT calculations. Physical Chemistry Chemical Physics 4(20), pp. 4937-4943. (10.1039/b204564h)
• Chiesa, M., Paganini, M. C., Giamello, E. and Murphy, D. M. 2002. O- radical ions on MgO: a tool for a structural description of the surface. Research on Chemical Intermediates 28(2-3), pp. 205-214. (10.1163/156856702320267118)
• Chiesa, M., Giamello, E., Paganini, M. C., Sojka, Z. and Murphy, D. M. 2002. Continuous wave electron paramagnetic resonance investigation of the hyperfine structure of O-17(2)- adsorbed on the MgO surface. Journal of Chemical Physics 116(10), pp. 4266-4274. (10.1063/1.1447907)

2001

• Chiesa, M., Paganini, M. C., Giamello, E. and Murphy, D. M. 2001. Partial ionization of cesium atoms at point defects over polycrystalline magnesium oxide. Journal of Physical Chemistry B 105(43), pp. 10457-10460. (10.1021/jp0118470)
• Murphy, D. M. and Rowlands, C. C. 2001. Recent applications of electron magnetic resonance (EMR) techniques in heterogeneous catalysis. Current Opinion in Solid State and Materials Science 5(1), pp. 97-104.
• Traa, Y., Murphy, D. M., Farley, R. D. and Hutchings, G. J. 2001. An EPR study on the enantioselective aziridination properties of a CuNaY zeolite. Physical Chemistry Chemical Physics 3(6), pp. 1073-1080. (10.1039/B010083H)

2000

• Piaggio, P. et al. 2000. Enantioselective epoxidation of (Z)-stilbene using a chiral Mn(III)-salen complex: effect of immobilisation on MCM-41 on product selectivity. Journal of the Chemical Society - Perkins Transactions 2 2000(10), pp. 2008-2015. (10.1039/B005752P)
• Giamello, E., Paganini, M. C., Chiesa, M., Murphy, D. M., Pacchioni, G., Soave, R. and Rockenbauer, A. 2000. N-2(-) radical anion reversibly formed at the surface of "electron-rich" alkaline-earth oxides. Journal of Physical Chemistry B 104(9), pp. 1887-1890. (10.1021/jp994126y)
• Fallis, I. A., Farley, R. D., Malik, K. M. A., Murphy, D. M. and Smith, H. J. 2000. Divalent first-row transition metal complexes of the rigid pendant-arm ligand 1,4,7-tris(2-aminophenyl)-1,4,7-triazacyclononane. Journal of the Chemical Society, Dalton Transactions 20, pp. 3632-3639. (10.1039/b005402j)

1999

• Jenkins, C. A. and Murphy, D. M. 1999. Thermal and photoreactivity of TiO2 at the gas-solid interface with aliphatic and aromatic aldehydes. Journal of Physical Chemistry B 103(6), pp. 1019-1026. (10.1021/jp982690n)